A dimerization reaction of ethylene is used to form 1-butene by the following reaction:
H2C=CH2+H2C=CH2⟶H3CCH2HC□CH2
The process is a liquid phase reaction that takes place 25∘C. The initial feed to the reactor is pure ethylene and 20% (mole-wise) of ethylene is converted to 1 -butene at equilibrium. Assuming the non-ideal solution behavior of the system can be described by:
Gᴱ/RT=AxBxE Where:
A is a scaling coefficient
XB is the mole fraction of 1-butene
XE is the mole fraction of ethylene