A 94.7-g sample of silver (s = 0.237 j/(g · °c)), initially at 348.25°c, is added to an insulated vessel containing 143.6 g of water (s = 4.18 j/(g · °c)), initially at 13.97°c. at equilibrium, the final temperature of the metal–water mixture is 22.63°c. how much heat was absorbed by the water? the heat capacity of the vessel is 0.244 kj/°c.