The free-base form of cocaine has a solubility of 1.00 g in 6.70 mL ethanol (CH3CH2OH). Calculate the molarity of a saturated solution of the free-base form of cocaine in ethanol.

Respuesta :

Given information : Free-base form of cocaine solubility 1.00 g in 6.70 mL ethanol.

We have to find molarity.

[tex] Molarity (M) =\frac{Moles of solute}{Volume of solution in L} [/tex]

To find molarity we need to first find moles of solute and volume of solution.

In our question solute is Cocaine(C17H21NO4) and ethanol (CH3CH2OH) is solvent.

Volume of solution = Volume of solute + Volume of solvent.

In our question , density of cocaine is not given that means amount of cocaine is very less as compared to that of solvent , so to find the volume of solution we can only consider volume of solvent that means we can take volume of solution as 6.70 mL.

Moles of solute cocaine (C17H21NO4) = [tex] \frac{Grams of solute}{Molar mass of solute} [/tex]

Molar mass of coacine (C17H21NO4) = 303.358 g/mol

Gram of solute given = 1 gram

[tex] Moles of solute = 1 gramC17H21NO4\times \frac{1 mol C17H21NO4}{303.358 gram C17H21NO4} [/tex]

Moles of solute C17H21NO4 = 0.00330 mol C17H21NO4

Volume of solution should be in L , so we will convert 6.70 mL to L

[tex] Volume of solution = 6.70 mL\times \frac{1 L}{1000 mL} [/tex]

Volume of solution = 0.0067 L

Now we can find molarity by plugging the moles of solute and volume of solution value in the formula.

[tex] Molarity (M) =\frac{Moles of solute}{Volume of solution in L} [/tex]

[tex] Molarity = \frac{(0.00330 mol)}{(0.0067 L)} [/tex]

Molarity = 0.49 mol/L or 0.49 M