Answer is: formula of the compound is C₁₂H₈O₅.
Chemical reaction: CₐHₓO + O₂ → aCO₂ + x/2H₂O.
n(CO₂) = m(CO₂) ÷ M(CO₂).
n(CO₂) = 53.7 g ÷ 44 g/mol.
n(CO₂) = 1.22 mol.
n(H₂O) = 8.45 g ÷ 18 g/mol.
n(H₂O) = 0.47 mol.
From reaction: n(C) = n(CO₂).
m(C) = 1.22 mol · 12 g/mol.
m(C) = 14.64 g.
From chemical reaction: n(H₂O) = 2n(H).
n(H) = 2 · 0.47 mol = 0.94 mol.
m(H) = 0.94 mol · 1g/mol = 0.94 g.
m(O) = 24.6 g - 0.94 g - 14.64 g = 9.02 g.
n(O) = 9.02 ÷ 16 g/mol = 0.56 mol.
n(C) : n(H) : n(O) = 1.22 mol : 0.94 mol : 0.56 mol /0.56.
n(C) : n(H) : n(O) = 2.18 : 1.68 : 1.