Respuesta :
The density of a unit cell lattice is calculated using the following formula:
[tex]\rho =\frac{mn}{a^{3}N_{A}}[/tex]...... (1)
Here, [tex]\rho[/tex] is density, m is molar mass or atomic weight, n is number of atoms per unit cell, a is edge length and [tex]N_{A}[/tex] is Avogadro's number.
For a body centered cubic lattice, number of atoms per unit cell is 2 and relation between edge length a and radius of atom r is as follows:
[tex]r=\frac{\sqrt{3}a}{4}[/tex] ...... (2)
Here, r is atomic radius and a is edge length.
Calculate edge length by rearranging equation (1) as follows:
[tex]a=\sqrt[3]{\frac{mn}{\rho N_{A}}}[/tex]
Density of metal is [tex]7.25 g/cm^{3}[/tex] and molar mass is 50.99 g/mol, putting the values,
[tex]a=\sqrt[3]{\frac{(50.99 g/mol)(2)}{(7.25 g/cm^{3})(6.023\times 10^{23} mol^{-1})}}=2.86\times 10^{-23} cm[/tex]
Therefore, edge length is [tex]2.86\times 10^{-23} cm[/tex], putting the value in equation (2) to calculate atomic radius.
[tex]r=\frac{\sqrt{3}a}{4}=\frac{\sqrt{3}(2.86\times 10^{-8} cm)}{4}=1.24\times 10^{-8} cm[/tex]
Therefore, atomic radius will be [tex]1.24\times 10^{-8} cm[/tex].
The atomic radius if the metal has a density of 7.25 g/cm3 and an atomic weight of 50.99 g/mol is 0.124 nm
Further explanation
Or a metal that has the body-centered cubic crystal structure, calculate the atomic radius if the metal has a density of [tex]7.25 g/cm^3[/tex]and an atomic weight of 50.99 g/mol.
The density of a metal may be calculated using the following equation:
[tex]\rho = \frac{mn}{a^3 N_A}[/tex]
Where:
[tex]\rho[/tex] is density, [tex]m[/tex] is molar mass, [tex]n[/tex] is atomic number per unit cell, [tex]a[/tex] is edge length and [tex]N_A[/tex] is Avogadro's number
Now, for the body-centered cubic crystal structure there are two atoms associated with each unit cell (i.e., [tex]n= 2[/tex]), and the atomic radius and unit cell edge length are related as
[tex]r = \frac{\sqrt{3}a }{4}[/tex]
Where:
[tex]r[/tex] is atomic radius and [tex]a[/tex] is edge length
Since the unit cell for the body-centered cubic crystal structure has cubic symmetry, [tex]V_C= a^3[/tex]. Substitution of the last two relationships into the first equation leads to
[tex]a = \sqrt[3]{\frac{mn}{\rho N_A} }[/tex]
[tex]a = \sqrt[3]{\frac{50.99 * 2}{7.25 *6.023 * 10^{23}} }= 2.86 * 10^{-23} cm[/tex]
and solving for [tex]R[/tex] yields
[tex]r = \frac{\sqrt{3}a }{4} = \frac{\sqrt{3}* 2.86*10^{-8} }{4}[/tex]
[tex]r = 1.24 * 10^-8cm = 0.124 nm[/tex]
Learn more
- Learn more about the body-centered cubic https://brainly.com/question/4501234
- Learn more about the atomic radius https://brainly.com/question/2631938
- Learn more about Metal Density https://brainly.com/question/2284124
Answer details
Grade: 9
Subject: chemistry
Chapter: Crystal structure
Keywords: the body-centered cubic, the atomic radius, Metal Density, an atomic weight, crystal structure