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The percentage yield is 72.8 %.
Step 1. Calculate the mass of Br₂
Mass of Br₂ = 20.0 mL Br₂ × (3.10 g Br₂/1 mL Br₂) = 62.00 g Br₂
Step 2. Calculate the theoretical yield
M_r: 159.81 266.69
2Al + 3Br₂ → 2AlBr₃
Moles of Br₂ = 62.00 g Br₂ × (1 mol Br₂/(159.81 g Br₂) = 0.3880 mol Br₂
Moles of AlBr₃ = 0.3880 mol Br₂ × (2 mol AlBr₃/(3 mol Br₂) = 0.2586 mol AlBr₃
Theor. yield of AlBr₃ = 0.2586 mol AlBr₃ × 266.99 g AlBr₃)/(1 mol AlBr₃)
= 69.05 g AlCl₃
Step 3. Calculate the percentage yield
% yield = (actual yield/theoretical yield) × 100 % = (50.3 g/69.05 g) × 100 %
= 72.8 %