Respuesta :
The formula for mole fraction is:
[tex]mole fraction of solute = \frac{number of moles of solute}{total number of moles of solution}[/tex] -(1)
The solubility of oxygen gas = 1.0 mmol/L (given)
1.0 mmol/L means 1.0 mmol are present in 1 L.
Converting mmol to mol:
[tex]1.00 mmol\times \frac{1 mol}{1000 mmol} = 0.001 mol[/tex]
So, moles of oxygen = 0.001 mol
For moles of water:
1 L of water = 1000 mL of water
Since, the density of water is 1.0 g/mL.
[tex]Density = \frac{mass}{volume}[/tex]
[tex]Mass = 1.0 g/ml\times 1000 mL = 1000 g[/tex]
So, the mass of water is 1000 g.
Molar mass of water = 18 g/mol.
Number of moles of water = [tex]\frac{1000 g}{18 g/mol} = 55.55 mol[/tex]
Substituting the values in formula (1):
[tex]mole fraction = \frac{0.001}{55.55+0.001}[/tex]
[tex]mole fraction = 1.8\times 10^{-5}[/tex]
Hence, the mole fraction is [tex]1.8\times 10^{-5}[/tex].
The solubility of oxygen gas in water at 40° C is 1.0 mmol/l of solution. The concentration in units of mole fraction is 1.80 × 10⁻⁵.
In 1 Liter of a solution, the solubility of 1.0 mmol/L is expressed as:
[tex]\mathbf{= 1.0 \ mmol \times \dfrac{1 \ mol}{1000 \ mmol} }[/tex]
= 0.001 mol of oxygen.
However, the moles of water in 1L is calculated as follows;
- We know that 1 L of water = 1000 mL of water.
- suppose we make an assumption that the density of the water is 1.0 g/mL
Then using the formula for density which is:
- density = mass/volume
Making mass the subject of the formula:
- Mass = density × volume
- Mass = 1.0 g/mL× 1000 mL
- Mass of water = 1000 g
Now, the number of moles of the water can be estimated using the formula:
number of moles = mass(g)/molar mass
The number of moles of water = 1000 g/ 18.02 g/mol
The number of moles of water = 55.49 moles
Finally, for the mole fraction of oxygen, we have:
[tex]{\text}mole fraction of oxygen = \dfrac{\text{moles of oxygen }}{\text{total moles in the system}}[/tex]
[tex]{\text}mole fraction of oxygen = \dfrac{\text{0.001 moles }}{\text{55.49 moles }}[/tex]
mole fraction of oxygen = 1.80 × 10⁻⁵.
Learn more about mole fractions here:
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