We assume that the volume of the molecules themselves in a gas sample is negligible compared to the bulk volume of the gas sample: this helps us to explain why gases are so compressible.
The volume of the actual molecules in a sample of gas is higher as compared to the bulk volume of the gas.
The volume of the actual molecules themselves in a sample of gas is larger as compared to the bulk volume of the gas overall because on the individual gas molecule, there is no pressure on it while on the other hand, the bulk volume of the gas has pressure on one another.
So we can conclude that the volume of the actual molecules in a sample of gas is higher as compared to the bulk volume of the gas.
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