Which of the following statements is FALSE? Which of the following statements is FALSE? Myoglobin is a single polypeptide chain folded about a heme prosthetic group. Hemoglobin is a tetramer, each of which binds a heme group. In both hemoglobin and myoglobin, iron is chelated by a tetrapyrole ring system. The iron in both hemoglobin and myoglobin has two coordination sites that bind to oxygen.