Question 5 A solution is prepared at 25°C that is initially 0.35M in chlorous acid HClO2, a weak acid with =Ka×1.110−2, and 0.29M in sodium chlorite NaClO2. Calculate the pH of the solution. Round your answer to 2 decimal places.

Respuesta :

Answer : The pH of the solution is, 1.88

Explanation : Given,

[tex]K_a=1.1\times 10^{-2}[/tex]

Concentration of [tex]HClO_2[/tex] = 0.35 M

Concentration of [tex]NaClO_2[/tex] = 0.29 M

First we have to calculate the value of [tex]pK_a[/tex].

The expression used for the calculation of [tex]pK_a[/tex] is,

[tex]pK_a=-\log [K_a][/tex]

Now put the value of [tex]K_a[/tex] in this expression, we get:

[tex]pK_a=-\log (1.1\times 1-^{-2})[/tex]

[tex]pK_a=2-\log (1.1)[/tex]

[tex]pK_a=1.96[/tex]

Now we have to calculate the pH of the solution.

Using Henderson Hesselbach equation :

[tex]pH=pK_a+\log \frac{[Salt]}{[Acid]}[/tex]

[tex]pH=pK_a+\log \frac{[NaClO_2]}{[HClO_2]}[/tex]

Now put all the given values in this expression, we get:

[tex]pH=1.96+\log (\frac{0.29}{0.35})[/tex]

[tex]pH=1.88[/tex]

Therefore, the pH of the solution is, 1.88