How many coulombs are required to plate a layer of chromium metal 0.28 mm thick on an auto bumper with a total area of 0.40 m2 from a solution containing CrO2−4? The density of chromium metal is 7.20 g/cm3.

Respuesta :

Explanation:

The given data is as follows.

Thickness = 0.28 mm = [tex]0.28 \times \frac{1}{10}[/tex] cm = 0.028 cm

Area = 0.40 [tex]m^{2}[/tex] = [tex]0.40 \times 10^{4} cm^{2}[/tex] = 4000 [tex]cm^{2}[/tex]

As, it is known that volume = area × thickness

So,             Volume = [tex]4000 cm^{2} \times 0.028 cm[/tex]      

                                = 112 [tex]cm^{3}[/tex]

As density is mass divided by volume. So, mass of chromium will be calculated as follows.

                   Density = [tex]\frac{mass}{volume}[/tex]  

            7.20 [tex]g/cm^{3}[/tex] = [tex]\frac{mass}{112 cm^{3}}[/tex]      

                      mass = 806.4 g

As, mass of 1 mole of chromium is 52 g. So, number of moles in 806.4 g of chromium will be as follows.

              No. of moles = [tex]\frac{mass}{molar mass}[/tex]                            

                                     = [tex]\frac{806.4 g}{52 g}[/tex]

                                     = 15.50 mol

In chromate ion, ([tex]CrO^{2-}_{4}[/tex]) charge on Cr is +6. It means that 6 electrons are needed to reduce [tex]Cr^{+6}[/tex] into Cr.

As, 1 mole of [tex]Cr^{+6}[/tex] ions require 6 moles of electrons. Therefore, moles of electrons for 15.50 mol will be calculated as follows.

                              6 × 15.50 mol = 93.04 mol

To calculate number of electrons we multiply number of moles by Avogadro's number as follows.

               [tex]93.04 mol \times 6.02 \times 10^{23}[/tex]

                      = [tex]560.13 \times 10^{23}[/tex]

                     = [tex]5.6 \times 10^{25}[/tex] electrons

There is magnitude of [tex]6.241 \times 10^{18}[/tex] times the charge on an electron is equal to 1 coulomb.

Hence, number of coulombs will be as follows.

              No. of coulombs = [tex]\frac{5.6 \times 10^{25}}{6.241 \times 10^{18}}[/tex]

                                           = [tex]0.897 \times 10^{7}[/tex] C

or,                                        = [tex]8.97 \times 10^{6}[/tex] C

Thus, we can conclude that [tex]8.97 \times 10^{6}[/tex] C are required to plate a layer of chromium metal with given data.