Calculate the Δ H°rxn for the decomposition of calcium carbonate to calcium oxide and carbon dioxide. Δ H°f [CaCO3(s)] = –1206.9 kJ/mol; Δ H°f [CaO(s)] = –635.1 kJ/mol; Δ H°f [CO2(g)] = –393.5 kJ/mol

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Answer:

[tex]\boxed{\text{178.3 kJ/mol}}[/tex]

Explanation

The formula for calculating the enthalpy change of a reaction by using the enthalpies of formation of reactants and products is

[tex]\Delta_{\text{r}}H^{\circ} = \sum \Delta_{\text{f}} H^{\circ} (\text{products}) - \sum\Delta_{\text{f}}H^{\circ} (\text{reactants})[/tex]

                         CaCO₃(s) ⟶ CaO(s) + CO₂(g)

ΔH°f/kJ·mol⁻¹:    -1206.9         -635.1    -393.5

[tex]\begin{array}{rcl}\Delta_{\text{r}}H^{\circ}& = & [(-635.1 + (-393.5)] - (-1206.9)\\& = & -1028.6 +1206.9\\& = & \mathbf{178.3}\\\end{array}\\\text{The enthalpy of decomposition is } \boxed{\textbf{178.3 kJ/mol}}[/tex]l}}

A decomposition reaction is a chemical reaction in which the reactants breaks into two or more products. The enthalpy of the decomposition reaction is 178.3 kJ/mol.

What is the enthalpy of reaction?

The enthalpy of reaction [tex]\rm (\Delta Hrxn)[/tex] is the difference between the product enthalpy and reactant enthalpy and is given in the units kilojoules per mole.

It can be calculated by the formula:

[tex]\rm \Delta H rxn = \sum \Delta H_{f}(products) - \sum \Delta H_{f}(reactants)[/tex]

The reaction can be shown as:

[tex]\rm CaCO_{3}(s) \rightarrow CaO(s) + CO_{2}(g)[/tex]

Given,

The enthalpy of formation of reactant (calcium carbonate) = -1206.9  

The enthalpy of formation of product (calcium oxide) = -635.1

The enthalpy of formation of product (carbon dioxide) =  -393.5

Substituting values in the above equation:

[tex]\begin{aligned}\rm \Delta H rxn &= [(-635.1 + (-393.5)] - (-1206.9)\\\\&= -1028.6 + 1206.9\\\\&= 178.3\end{aligned}[/tex]

Therefore, the enthalpy of the decomposition is 178.3 kJ/mol.

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