At a particular temperature, K 5.0 x 10-6 for the reaction 2CO2(9) 2CO(9) +02(9) If 3.0 moles of CO2 is initially placed into a 5.0-L vessel, calculate the equilibrium concentrations of all species. CO2] CO] O2l [02]-

Respuesta :

Answer : The concentration of [tex]CO_2,CO\text{ and }O_2[/tex] at equilibrium will be, 0.598 M, 0.00216 M and 0.00108 M respectively.

Explanation : Given,

Equilibrium constant = [tex]2.0\times 10^{-6}[/tex]

tex]\text{Concentration of }CO_2=\frac{\text{Moles of }CO_2}{\text{Volume of solution}}=\frac{3.0mole}{5.0L}=0.6mole=0.6M[/tex]

The balanced equilibrium reaction is,

                      [tex]2CO_2(g)\rightleftharpoons 2CO(g)+O_2(g)[/tex]

Initial conc.     0.6 M                 0             0

At eqm.        (0.6-2x) M          2x M         x M

The expression of equilibrium constant for the reaction will be:

[tex]K_c=\frac{[CO]^2[O_2]}{[CO_2]^2}[/tex]

Now put all the values in this expression, we get :

[tex]2.0\times 10^{-6}=\frac{(2x)^2\times (x)}{(0.6-2x)^2}[/tex]

By solving the term 'x', we get:

[tex]x=0.00108M[/tex]

Concentration of [tex]CO_2[/tex] at equilibrium = [tex](0.6-2x)M=[0.6-2(0.00108)]M=0.598M[/tex]

Concentration of [tex]CO[/tex] at equilibrium = [tex](2x)M=[2(0.00108)]M=0.00216M[/tex]

Concentration of [tex]O_2[/tex] at equilibrium = [tex](x)M=0.00108M[/tex]