Determine the number of unpaired electrons expected for [Fe(NO2)6]3−and for [FeF6]3− in terms of crystal field theory.

Respuesta :

Answer:

A. One unpaired electron

B. 5 unpaired electrons

Explanation:

In A ,Fe is in +3 oxidation state and Electronic configuration- [Ar]3d5

And NO2 is a strong field ligand hence it causes pairing in t2g orbitals and results one unpaired electron in dZX orbital.

In B, also Fe is in +3 oxidation state but F is weak field ligand hence causes no pairing of Electrons hence it results 5 unpaired electrons with electronic configuration t2g^3 eg^2

Lanuel

The number of unpaired electrons that are expected for [tex][Fe(NO_2)_6]_3[/tex] is equal to one (1).

What is crystal field theory?

Crystal field theory (CFT) can be defined as a model that describes the breaking of orbital degeneracy of an electron or bonding interaction in transition metals due to the presence of ligands.

For [tex][Fe(NO_2)_6]_3[/tex]:

The oxidation state of iron (Fe) is +3 and its electronic configuration is given by [tex][Ar]_3d_5[/tex]. Also, [tex]NO_2[/tex] represents a strong field ligand and as such it has one (1) unpaired electron in the [tex]d_{ZX}[/tex] orbital.

For [tex][FeF_6]_3[/tex]:

The oxidation state of iron (Fe) is +3 and its electronic configuration is given by [tex][Ar]_3d_5[/tex]. Also, [tex]F[/tex] represents a weak field ligand and as such it has five (5) unpaired electron.

Read more on electrons here: brainly.com/question/377844