Respuesta :
Answer:
The answer to your question is: ΔHrxm = -23.9 kJ
Explanation:
Data:
2Fe(s)+3/2O2(g)→Fe2O3(s), ΔH = -824.2 kJ (1)
CO(g)+1/2O2(g)→CO2(g) ΔH = -282.7 kJ (2)
Reaction:
Fe2O3(s)+3CO(g)→2Fe(s)+3CO2(g)
We invert (1) and change the sign of ΔH
Fe2O3(s) → 2Fe(s)+3/2O2(g) ΔH = 824.2 kJ
We multiply (2) by 3
3( CO(g)+1/2O2(g)→CO2(g) ΔH = -282.7 kJ) (2)
3CO(g)+3/2O2(g)→3CO2(g) ΔH = -848.1 kJ
We add (1) and (2)
Fe2O3(s) → 2Fe(s)+3/2O2(g) ΔH = 824.2 kJ
3CO(g)+3/2O2(g)→3CO2(g) ΔH = -848.1 kJ
Fe2O3(s) + 3CO(g)+3/2O2(g) → 2Fe(s)+3/2O2 + 3CO2(g)
Simplify
Fe2O3(s)+3CO(g)→2Fe(s)+3CO2(g) and ΔHrxm = -23.9 kJ
The enthalpy of reaction (ΔHrxn) of the reaction Fe₂O₃(s) + 3CO → 2Fe(s) + 3CO₂(g) calculated from the given enthalpies of the 2 reactions is -23.9 kJ.
We need to find the enthalpy of reaction (ΔHrxn) of the following reaction:
Fe₂O₃(s) + 3CO → 2Fe(s) + 3CO₂(g) (1)
We have the enthalpies of the reactions:
2Fe(s) + 3/2O₂(g) → Fe₂O₃(s) ΔH₁ = -824.2 kJ (2)
CO(g) + 1/2O₂(g) → CO₂(g) ΔH₂ = -282.7 kJ (3)
To calculate the ΔHrxn of equation (1) we must modify equations (2) and (3).
First, we need to invert equation (2) so the Fe₂O₃(s) be in the reactants rather than in the products. After doing this, the sign of ΔH₁ will change:
Fe₂O₃(s) → 2Fe(s) + 3/2O₂(g) ΔH₁ = 824.2 kJ (4)
Now we have the Fe₂O₃(s) in the reactants side as in reaction (1).
Second, we need to add a coefficient of 3 before the CO and CO₂, so we need to multiply equation (3) by 3.
3*[CO(g) + 1/2O₂(g) → CO₂(g)]
3CO(g) + 3/2O₂(g) → 3CO₂(g)
This also applies for ΔH₂ = -282.7 kJ:
[tex] \Delta H_{2} = 3*(-282.7) kJ = -848.1 kJ [/tex]
Hence, reaction (3) is now:
3CO(g) + 3/2O₂(g) → 3CO₂(g) ΔH₂ = -848.1 kJ (5)
Now we have the coefficients of 3 before CO and CO₂ as in equation (1).
Finally, by adding equations (4) and (5) we can get equation (1)
Fe₂O₃(s) + 3CO(g) + 3/2O₂(g) → 2Fe(s) + 3/2O₂(g) + 3CO₂(g)
Fe₂O₃(s) + 3CO(g) → 2Fe(s) + 3CO₂(g) (1)
We get the reaction (1). The enthalpy of reaction is given by the sum of ΔH₁ (eq 4) and ΔH₂ (eq 5).
[tex] \Delta H_{rxn} = \Delta H_{1} + \Delta H_{2} = 824.2 kJ + (-848.1 kJ) = -23.9 kJ [/tex]
Therefore, the ΔHrxn for the reaction (1) is -23.9 kJ.
You can find more about the enthalpy of reaction here:
- https://brainly.com/question/1657608?referrer=searchResults
- https://brainly.com/question/11753370?referrer=searchResults
I hope it helps you!
