The automobile fuel called E85 consists of 85 % ethanol and 15 % gasoline. E85 can be used in so-called "flex-fuel" vehicles (FFVs), which can use gasoline, ethanol, or a mix as fuels. Assume that gasoline consists of a mixture of octanes (different isomers of C8H18), that the average heat of combustion of C8H18(l) is 5400 kJ/mol, and that gasoline has an average density of 0.70 g/mL. The density of ethanol is 0.79 g/mL. By using the information given, calculate the energy produced by combustion of 1.5 L of gasoline.

Respuesta :

Answer:

[tex]4.974\times 10^{3} kJ[/tex] of energy is produced by combustion of 1.5 L of gasoline.

Explanation:

The average heat of combustion of liquid octane = [tex]\Delta H_{comb}=5400 kJ/mol[/tex]

Density of gasoline = 0.70 g/mL

Mass of gasoline with volume 1.5 L be m

V = Volume = 1.5 L = 1500 mL

[tex]Density=\frac{Mass}{Volume}[/tex]

[tex]0.70 g/ml=\frac{m}{1500 mL}[/tex]

[tex]m=0.70 g/mL\times 1500 mL=1050 g[/tex]

Since gasoline consists of a mixture of octanes. We can treat gasoline as a compound as octane.

Moles of octane = [tex]\frac{1050 g}{114 g/mol}=9.2105 mol[/tex]

Energy produced by combustion of  9.2105 mol of gasoline:

[tex]\Delta H_{comb}\times 9.2105 mol[/tex]

[tex]=5400 kJ/mol\times 9.2105 mol=49,736.84 kJ\approx 4.974\times 10^{3} kJ[/tex]