Consider a mixture of air and gasoline vapor in a cylinder with a piston. The original volume is 42 cm3. If the combustion of this mixture releases 927 J of energy, to what volume (in L) will the gases expand against a constant pressure of 656 torr if all the energy of combustion is converted into work to push back the piston?

Respuesta :

Explanation:

Relation between work, pressure and volume is as follows.

                    W = [tex]-P \Delta V[/tex]

where,       W = work = -927 J (as energy is released so, work is done by the system)

                  P = pressure = 656 torr

                     = [tex]8.74 \times 10^{4}[/tex] Pa          (as 1 torr = 133.3 Pa)

              Initial volume [tex](V_{1})[/tex] = 42 [tex]cm^{3}[/tex]

                                = [tex]42 \times 10^{-6} m^{3}[/tex]           (as 1 m = 100 cm)

Hence, calculate the final volume as follows.

                W = [tex]-P \Delta V[/tex]

           -927 J = [tex]-8.74 \times 10^{4} Pa \times (V_{2} - 42 \times 10^{-6} m^{3})[/tex]

           [tex]106.06 \times 10^{-4} = V_{2} - 0.42 \times 10^{-4}[/tex]

                     [tex]V_{2}[/tex] = [tex]106.48 \times 10^{-4} m^{3}[/tex]

                                      = 10.6 L            (as 1 [tex]m^{3}[/tex] = 1000 L)

                                      = 11 L (approx)

Thus, we can conclude that the gases expand 11 L against a constant pressure of 656 torr.