The deck is composed of 24 cards. Each value appears four times (4 aces, 4 kings, 4 queens, 4 jacks, 4 tens and 4 nines) and each suit appears six times (for each suit we have the nine, the ten, the jack, queen, king and ace).
Since there are 4 jacks out of 24 cards, the probability of picking a jack is
[tex]\dfrac{4}{24}=\dfrac{1}{6}[/tex]
Since there are 6 spades out of 24 cards, the probability of picking a spade is
[tex]\dfrac{6}{24}=\dfrac{1}{4}[/tex]