The equilibrium 2NO(g)+Cl2(g)⇌2NOCl(g) is established at 500 K. An equilibrium mixture of the three gases has partial pressures of 9.10×10−2 atm , 0.174 atm , and 0.24 atm for NO, Cl2, and NOCl, respectively. Part APart complete Calculate Kp for this reaction at 500.0 K. Express your answer using two significant figures. Kp = 40 Previous Answers Correct Part B If the vessel has a volume of 6.00 L , calculate Kc at this temperature. Express your answer using two significant figures.

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Answer:

For A: The [tex]K_p[/tex] for the given reaction is [tex]4.0\times 10^1[/tex]

For B: The [tex]K_c[/tex] for the given reaction is 1642.

Explanation:

The given chemical reaction follows:

[tex]2NO(g)+Cl_2(g)\rightleftharpoons 2NOCl(g)[/tex]

  • For A:

The expression of [tex]K_p[/tex] for the above reaction follows:

[tex]K_p=\frac{(p_{NOCl})^2}{(p_{NO})^2\times p_{Cl_2}}[/tex]

We are given:

[tex]p_{NOCl}=0.24 atm\\p_{NO}=9.10\times 10^{-2}atm=0.0910atm\\p_{Cl_2}=0.174atm[/tex]

Putting values in above equation, we get:

[tex]K_p=\frac{(0.24)^2}{(0.0910)^2\times 0.174}\\\\K_p=4.0\times 10^1[/tex]

Hence, the [tex]K_p[/tex] for the given reaction is [tex]4.0\times 10^1[/tex]

  • For B:

Relation of [tex]K_p[/tex] with [tex]K_c[/tex] is given by the formula:

[tex]K_p=K_c(RT)^{\Delta ng}[/tex]

where,

[tex]K_p[/tex] = equilibrium constant in terms of partial pressure = [tex]4.0\times 10^1[/tex]

[tex]K_c[/tex] = equilibrium constant in terms of concentration = ?

R = Gas constant = [tex]0.0821\text{ L atm }mol^{-1}K^{-1}[/tex]

T = temperature = 500 K

[tex]\Delta ng[/tex] = change in number of moles of gas particles = [tex]n_{products}-n_{reactants}=2-3=-1[/tex]

Putting values in above equation, we get:

[tex]4.0\times 10^1=K_c\times (0.0821\times 500)^{-1}\\\\K_c=\frac{4.0\times 10^1}{(0.0821\times 500)^{-1})}=1642[/tex]

Hence, the [tex]K_c[/tex] for the given reaction is 1642.

For this reaction, the Kc is 1700.

What is Kp?

Kp is use to denote the equilibrium constant in a gas phase reaction. We  have the values of the partial pressures as follows;

PNO = 9.10×10−2 atm

PCl2 = 0.174 atm

PNOCl =  0.24 atm

Now;

Kp = (PNOCl )^2/(PNO)^2 * PCl2

Kp = (0.24 atm)^2/( 9.10×10−2 atm)^2 *  0.174 atm

Kp =40.86

Now;

Kp=Kc(RT)^Δng

Kc = Kp/(RT)^Δng

Kc = 40.86/(0.082 * 500)^-1

Kc = 1700

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