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1. If you look at a reaction equation for a Fischer esterification reaction, you cannot tell where the oxygen comes from (acid or alcohol). Knowing the mechanism of this reaction, devise an experiment using O18, to help prove unequivocally where the oxygen comes from. 2 The Fischer Esterification is highly reversible and the products are only, slightly favored. State two procedures you did to help drive the reaction to the ester. 3. A student forgot to remove their silica gel beads before distillation of ester product. After distillation, his product was cloudy, indicating it was wet. Why

Respuesta :

Manetho

Answer:

Explained

Explanation:

In the experiment, an (18)O-labelled alcohol R('18)OH is used with normal unlabeled carboxylic acid RC(16)O2H:

The esterification reaction is:  

(note: the bracketed values are atomic masses)

RC(16)O_2H + R'(18)OH => RC16O18OR' + H_2(16)O

Since the alcohol is the nucleophile in this nucleophilic substitution reaction, it adds to the carbonyl group of the carboxylic acid and the (18)O atom becomes incorporated into the ester product, while the (16)OH group of the carboxylic acid is expelled as H_2(16)O.

By using mass spectroscopy to measure the mass of the ester and water products, it can be shown that each ester molecule contains one (18)O atom and one (16)O atom, while the water molecules contains only (16)O atoms.

This would prove unequivocally that the ester contains one O atom from the carboxylic acid and one O atom from the alcohol, while the water contains only O atoms from the carboxylic acid.

The two procedures that help drive the reaction to the ester are;

By removing the water produced during the reaction from the system.

By adding excess amount of alcohol.

What is Fischer esterification reaction?

Fischer Esterification reaction is defined as an organic reaction used to convert carboxylic acids in the presence of excess alcohol and a strong acid catalyst to produce an ester as the final product along with water.

1) In the experiment, an (18) O-labelled alcohol R'OH is used with normal unlabeled carboxylic acid RCOOH:

RCOOH + R'OH ⇄ RCOOR' + H₂O

We will use mass spectroscopy to measure the mass of the ester and water products, it can be shown that each ester molecule contains one O(18) atom and one O(16) atom, while the water molecules contains only O(16) atoms.

This experiment would prove unequivocally that the ester contains one O atom from the carboxylic acid and one O atom from the alcohol, while the water contains only O atoms from the carboxylic acid.

2) The two procedures that I will do to help drive the reaction to ester is;

  • By removing the water produced during the reaction from the system.
  • By adding excess amount of alcohol.

3) Silica gel is composed of tiny grain-like silica structures packed in small paper bags. Now, Silica gel absorbs moisture from the air and protects our things from unwanted humidity effects.

Finally the reason why after distillation, his product was cloudy is because using silica beads will remove the water that is produced during the reaction and gives off a dry and pure product upon distillation.

Read more about Esterification at; https://brainly.com/question/14028062

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