Carbon-14, which is present in all living tissue, radioactively decays via a first-order process. A one-gram sample of wood taken from a living tree gives a rate for carbon-14 decay of 13.6 counts per minute. If the half-life for carbon-14 is 5720 years, how old is a wood sample that gives a rate for carbon-14 decay of 4.4 counts per minute?

Respuesta :

Answer : The age of sample is [tex]9.33\times 10^3\text{ years}[/tex]

Explanation :

Half-life = 5720 years

First we have to calculate the rate constant, we use the formula :

[tex]k=\frac{0.693}{t_{1/2}}[/tex]

[tex]k=\frac{0.693}{5720\text{ years}}[/tex]

[tex]k=1.21\times 10^{-4}\text{ years}^{-1}[/tex]

Now we have to calculate the age of sample.

Expression for rate law for first order kinetics is given by:

[tex]t=\frac{2.303}{k}\log\frac{a}{a-x}[/tex]

where,

k = rate constant  = [tex]1.21\times 10^{-4}\text{ years}^{-1}[/tex]

t = age of the sample  = ?

a = let initial amount of the reactant  = 13.6 counts per min

a - x = amount left after decay process = 4.4 counts per min

Now put all the given values in above equation, we get

[tex]t=\frac{2.303}{1.21\times 10^{-4}}\log\frac{13.6}{4.4}[/tex]

[tex]t=9327.8\text{ years}=9.33\times 10^3\text{ years}[/tex]

Therefore, the age of sample is [tex]9.33\times 10^3\text{ years}[/tex]

The age of the wood sample that gives a rate for carbon-14 decay of 4.4 counts per minute is 9.33 x 10³ years.

What is the rate constant for the process?

We know the formula for the rate constant, k is given as,

[tex]k = \dfrac{0.693}{t_{(1/2)}}[/tex]

Half-life, [tex]t_{(1/2)} = 5720\ year[/tex]

[tex]k = \dfrac{0.693}{5720}\\\\k = 1.2115\times 10^{-4}\rm\ year^{-1}[/tex]

What is the age of the sample?

We know that the expression for rate law for first-order kinetics is given by,

[tex]t = \dfrac{2.303}{k}\rm log\dfrac{a}{a-x}[/tex]

Half-life, [tex]t_{(1/2)} = 5720\ year[/tex]

Rate constant, k = 1.21 x 10⁻⁴ year⁻¹

The initial amount of sample, a = 13.6 counts per min

Amount after decay process, (a-x) =  4.4 counts per min

[tex]t = \dfrac{2.303}{1.2115\times 10^{-4}\rm\ year^{-1}}\rm log\dfrac{13.6}{4.4}\\\\t = 9.33 \times 10^3\ years[/tex]

Hence, the age of the wood sample that gives a rate for carbon-14 decay of 4.4 counts per minute is 9.33 x 10³ years.

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