Constant-volume calorimeters are sometimes calibrated by running a combustion reaction of known ΔE and measuring the change in temperature. For example, the combustion energy of glucose is 15.57 kJ/g. When a 1.500 g sample of glucose burns in a constant volume calorimeter, the calorimeter temperature increases from 21.45 to 23.34°C. Find the total heat capacity of the calorimeter (in kJ/K).

Respuesta :

Answer:

he total heat capacity of the calorimeter is - 0.09 kJ/K

Explanation:

Given information

the combustion energy of glucose E = 15.57 kJ/g

mass of glucose, m = 1.500 g

initial temperature, [tex]T_{1}[/tex] = 21.45[tex]^{o} C[/tex]

final temperature [tex]T_{2}[/tex] = 23.34[tex]^{o} C[/tex]

the heat capacity of the calorimeter can be determined by

C = Q/ΔT

where

C = heat capacity (kJ/[tex]^{o} C[/tex])

Q = quantity of the heat (kJ)

ΔT = temeperature difference ([tex]^{o} C[/tex])

Q = E m

   = - (15.57 kJ/g)(1.500 g)

   = 23.355 kJ

ΔT = [tex]T_{2}[/tex]-[tex]T_{1}[/tex]

     = 23.34[tex]^{o} C[/tex] - 21.45[tex]^{o} C[/tex]

     = 1.89[tex]^{o} C[/tex]

Since the question ask to answer in kJ/k, we need to convert the temperature from celcius to kelvin by adding 273. thus,

ΔT = 1.89[tex]^{o} C[/tex] + 273

     = 274.89 K

C = Q/ΔT

  = - 23.355 kJ/274.89 K

  = - 0.09 kJ/K