Our data are,
State 1:
[tex]P_1= 10psi=68.95kPa\\V_1 = 1ft^3=0.02831m^3\\T_1 = 100\°F = 310.93K[/tex]
State 2:
[tex]P_2 =5psi=34.474kPa\\V_2 = 3ft^3=0.0899m^3[/tex]
We know as well that [tex]3BTU=3.16kJ/K[/tex]
To find the mass we apply the ideal gas formula, which is given by
[tex]P_1V_1=mRT_1[/tex]
Re-arrange for m,
[tex]m= \frac{P_1V_1}{RT_1}\\m= \frac{68.95*0.02831}{(0.287)310.9}\\m=0.021893kg=0.04806lbm\\[/tex]
Because of the pressure, temperature and volume ratio of state 1 and 2, we have to
[tex]\frac{P_1V_1}{T_1}=\frac{P_2V_2}{T_2}[/tex]
Replacing,
[tex]T_2 = \frac{P_2V_2}{P_1V_1}T_1\\T_2 =\frac{34.474*0.0844}{68.95*0.02831}*310.93\\T_2 = 464.217K=375.5\°F[/tex]
For conservative energy we have, (Cv = 0.718)
[tex]W = m C_v = 0.718 \Delta T +dw\\dw = W - mv\Delta T\\dw = 3.16-(0.0218*0.718)(454.127-310.93)\\dw = 0.765kJ=0.72BTU[/tex]