A chemical reaction has an increase in entropy and a decrease in enthalpy. What is known about the spontaneity of the reaction?

Respuesta :

Hagrid

A chemical reaction has an increase in entropy and a decrease in enthalpy. The chemical reaction is spontaneous. A chemical reaction is spontaneous if it has an entropy greater than zero and an enthalpy less than 0

Answer: Reaction is spontaneous at all temperatures.

Explanation:

According to Gibb's equation:

[tex]\Delta G=\Delta H-T\Delta S[/tex]

[tex]\Delta G[/tex] = Gibbs free energy

[tex]\Delta H[/tex] = enthalpy change

[tex]\Delta S[/tex] = entropy change

T = temperature in Kelvin

[tex]\Delta G[/tex]= +ve, reaction is non spontaneous

[tex]\Delta G[/tex]= -ve, reaction is spontaneous

[tex]\Delta G[/tex]= 0, reaction is in equilibrium

Thus when [tex]\Delta H[/tex] = -ve (decrease in enthalpy)

[tex]\Delta S[/tex] = +ve (increase in entropy)

[tex]\Delta G=(-ve)-T(+ve)[/tex]

[tex]\Delta G=(-ve)(-ve)=-ve[/tex]  

Thus Reaction is spontaneous at all temperatures.