(a) Draw the best Lewis structure(s) for the nitrite ion, NO2-. (b) With what allotrope of oxygen is it isoelectronic? (c) What would you predict for the lengths of the bonds in NO2- relative to N¬O single bonds and double bonds?

Respuesta :

Answer:

(a) [tex]NO_{2}^{-}[/tex] ion has two resonance structures.

(b) [tex]O_{3}[/tex] molecule is isoelectronic.

(c) Due to resonance N-O  bond is having double bond character.

Explanation:

(a)

The Lewis structure of [tex]NO_{2}^{-}[/tex] is as follows.

(In attachment)

(b)

Isoelectronic means both species having same number of electrons .

[tex]NO_{2}^{-}[/tex] is isoelectronic with [tex]O_{3}[/tex] .

Both these molecules having 24 electrons and 18 valence electrons.

Hence, [tex]O_{3}[/tex]  molecule isoelectronic with [tex]NO_{2}^{-}[/tex].

(c)

The bond length of N-O single bond is more than the N-O double bond.

Due to the resonance structure of [tex]NO_{2}^{-}[/tex] N-O bond has double bond character.

Ver imagen FlaxenReflection