The vapor pressure of pure acetone is 266 torr. When a non-volatile solute is added, the vapor pressure of acetone above the solution falls to 214 torr. What is the mole fraction of the non-volatile solute in the solution?

Respuesta :

Answer : The mole fraction of the non-volatile solute in the solution is 0.195

Explanation :

According to the relative lowering of vapor pressure, the vapor pressure of a component at a given temperature is equal to the mole fraction of that component of the solution multiplied by the vapor pressure of that component in the pure state.

Formula used :

[tex]\frac{\Delta p}{p^o}=X_B[/tex]

[tex]\frac{p^o-p_s}{p^o}=X_B[/tex]

where,

[tex]p^o[/tex] = vapor pressure of the pure solvent (acetone)  = 266 torr

[tex]p_s[/tex] = vapor pressure of the solution = 214 torr

[tex]X_B[/tex] = mole fraction of solute  = ?

Now put all the given values in the above formula, we get:

[tex]\frac{p^o-p_s}{p^o}=X_B[/tex]

[tex]\frac{266-214}{266}=X_B[/tex]

[tex]X_B=0.195[/tex]

Therefore, the mole fraction of the non-volatile solute in the solution is 0.195

The mole fraction of the non-volatile solute in the solution is 0.195

What is the vapor pressure?

The vapor pressure is the pressure exerted by vapor in a closed system.

By the law of vapor pressure

[tex]\dfrac{\Delta P}{P\circ}=X_B\\\\\\ \dfrac{P^\circ -P_s}{P^\circ} =X_B \\\\\\\dfrac{266 - 214}{266}=X_B\\\\X_B = 0.195[/tex]

Thus, the mole fraction of non-volatile solute is 0.195.

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