Given the following notation for an electrochemical cell Pt(s) | H2(g) | H+(aq) || Ag+(aq) | Ag(s) what is the balanced overall (net) cell reaction?

Respuesta :

Answer:

H₂(g) + 2Ag⁺(aq) → 2Ag(s) + 2H⁺ (aq)

Explanation:

In an electrochemical cell , the cell notation is written in a way , that first is the oxidation half is written followed by the reduction , which are separated by the salt bridge ,

hence , from the question , the cell notation is given as -  

Pt(s) | H₂(g) | H⁺(aq) || Ag⁺(aq) | Ag(s)

Hence , from the above reaction , the oxidation half cell and reduction half cell as given as -

Oxidation -

H₂(g) → H⁺ (aq)

Reduction -

Ag⁺(aq) → Ag(s)

Now , balancing the reaction , by adding electrons on the required side -

Oxidation -

H₂(g) → 2H⁺ (aq) + 2e⁻

Reduction -

Ag⁺(aq) + e⁻ → Ag(s)

The above reaction can also be written as -

2Ag⁺(aq) + 2e⁻ → 2Ag(s)

Now , to overall cell reaction can be written as adding the respective half cells and eliminating the electrons , i.e. ,

H₂(g) + 2Ag⁺(aq) → 2Ag(s) + 2H⁺ (aq)