How much energy must be removed from a 125 g sample of benzene (molar mass= 78.11 g/mol) at 425.0 K to liquify the sample and lower the temperature to 335.0 K? The following physical data may be useful.ΔHvap = 33.9 kJ/molΔHfus = 9.8 kJ/molCliq = 1.73 J/g°CCgas = 1.06 J/g°CCsol = 1.51 J/g°CTmelting = 279.0 KTboiling = 353.0 K

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Explanation:

First, we will calculate the number of moles of benzene as follows.

      No. of moles = [tex]\frac{mass}{\text{molar mass}}[/tex]

                            = [tex]\frac{125 g}{78.11 g}[/tex]

                            = 1.60 moles

We assume that the heat energy is removed from the benzene in three separate steps:

1) In cooling the gaseous sample from 425K to 353K (its boiling point)

2) In liquefying the sample at 353 K

3) In cooling the liquid from 353 K to 335 K

So, we will first calculate the energy removed from the benzene at each step, then add them together to find the total amount of energy removed from the benzene.

1)  Q = [tex]m \times C \times \Delta T[/tex]

       = 125 x 1.06 x (425 - 353)

       = 9540J

or,    = 9.540 kJ        (as 1 kJ = 1000 J)

2) Also,  Q = [tex]\Delta H_{vap} \times 1.6 mol[/tex]

                  = 33.9 x 1.6

                 = 54.24 kJ

3)  Q = [tex]m \times C \times \Delta T[/tex]

       = 125 x 1.73 x (353 - 335)

       = 3893J

       = 3.893kJ

Hence, total = 9.540 + 54.240 + 3.893 = 67.673 kJ

Thus, we can conclude that 67.673 kJ energy must be removed from a 125 g given sample of benzene under the given conditions.

67.673 kJ energy must be removed from a 125 g given sample of benzene under the given conditions.

Number of moles:

It is defined as the ratio of given mass over molar mass.

Given:

Mass = 125g

Molar mass =78.11g/mol

[tex]\text{Number of moles}=\frac{\text{given mass}}{\text{molar mass}}\\\\ \text{Number of moles}=\frac{125g}{78.11g/mol}\\\\ \text{Number of moles}=1.60 moles[/tex]

Calculation of heat energy:

The heat energy is removed from the benzene in three separate steps:

  • In cooling the gaseous sample from 425K to 353K (its boiling point).
  • In liquefying the sample at 353 K.
  • In cooling the liquid from 353 K to 335 K.

1) In order to calculate the energy we will use specific heat formula which is given as:

[tex]Q=m*c*\triangle T[/tex]

Substituting values in this formula

[tex]Q=m*c*\triangle T\\\\ Q= 125 * 1.06 * (425 - 353)\\\\ Q= 9540J=9.540kJ[/tex]

2)

[tex]Q = H_{vap}*1.6mol\\\\Q=33.9*1.6\\\\Q=54.24kJ[/tex]

3)  

[tex]Q=m*c*\triangle T\\\\Q=125*7.73*(353-335)\\\\Q=3893J=3.893kJ[/tex]

Thus, total  [tex]Q= 9.540 + 54.240 + 3.893 = 67.673 kJ[/tex]

We can conclude that 67.673 kJ energy must be removed from a 125 g given sample of benzene under the given conditions.

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