An aqueous soulution contains 30% C3H7OH and 70% water by mass. what are the mole fractions of each substance in the solution?

Respuesta :

Answer:

Mole fraction of water = 0.88

Mole fraction of [tex]\chi_{C_{3}H_{7}OH}[/tex] = 0.12

Explanation:

30% [tex]C_{3}H_{7}OH[/tex] means 30 g of [tex]C_{3}H_{7}OH[/tex] is present in 100 g of solution.

70% [tex]H_{2}O[/tex](water) means 70 g of water is present in 100 g of solution

[tex]n=\frac{given\ mass}{molar\ mass}[/tex]

Calculation of MOLES

Molar mass of  [tex]H_{2}O[/tex] = 18 g/mol

[tex]n_{water}=\frac{70}{18}[/tex]

[tex]n_{water} = 3.89\ moles[/tex]

moles of water = 3.89 moles

Molar mass of  [tex]C_{3}H_{7}OH[/tex] = 3(12) + 7(1) + 1(16) +1(1)

                                                                  = 36 +7+16+1

molar mass of [tex]C_{3}H_{7}OH[/tex] = 60 g/mol

[tex]n_{C_{3}H_{7}OH}=\frac{30}{60}[/tex]

[tex]n_{C_{3}H_{7}OH} = 0.5\ moles[/tex]

moles of [tex]C_{3}H_{7}OH[/tex] = 0.5 moles

total moles of solution = 0.5 + 3.89 = 4.39 moles

Calculation of MOLE FRACTION

Formula for mole fraction is :

[tex]\chi=\frac{moles\ of\ solute}{moles\ of\ solution}[/tex]

[tex]\chi_{water}=\frac{moles\ of\ water}{Total\ moles}[/tex]

[tex]\chi_{water}=\frac{3.89}{4.39}[/tex]

[tex]\chi_{water}= 0.88[/tex]

Similarly,

[tex]\chi_{C_{3}H_{7}OH} = \frac{moles\ of\ C_{3}H_{7}OH}{Total\ moles}[/tex]

[tex]\chi_{C_{3}H_{7}OH} = \frac{0.5}{4.39}[/tex]

[tex]\chi_{C_{3}H_{7}OH} = \frac{0.5}{4.39}[/tex]

[tex]\chi_{C_{3}H_{7}OH} = 0.12[/tex]

Mole fraction of water = 0.88

Mole fraction of [tex]\chi_{C_{3}H_{7}OH}[/tex] = 0.12

Note :

[tex]\chi_{C_{3}H_{7}OH} + \chi_{H_{2}O} = 1[/tex]