Use the conservation of energy to explain why the temperature of a well-insulated gas increases when it is compressed-say by pushing down on a piston-whereas the temperature decreases when the gas explands. Show your reasoning.

Respuesta :

Answer:

See explanation.

Explanation:

In thermodynamic we used to use the expression [tex] \varDelta U=Q+W[/tex] for conservation of energy that is the first law of thermodynamics with [tex] \varDelta U [/tex] the internal energy of the system (U is directly proportional to temperature), Q the net heat and W the net work. In our case Q=0 because the gas is insulated so there's no exchange of heat with the environment:

[tex]\varDelta U=W [/tex]

Work for perfect gases is approximtely [tex] -P\Delta V[/tex]

with P pressure (is constant in our case and always positive) and V volume.

[tex] \varDelta U=-P\Delta V=-P(V_{final}-V_{initial})[/tex]

Note if the gas is compressed [tex] V_{final}-V_{initial}[/tex] is negative (because [tex] V_{final}<V_{initial}[/tex]) so [tex] \varDelta U[/tex] is positive that means U is going to increase so the temperature too because they are proportional.

In the other case if the gas expands [tex] V_{final}-V_{initial}[/tex]  is positive (because [tex] V_{final}>V_{initial}[/tex]) and [tex]\varDelta U [/tex] is negative so U is going to decrease and temperature too.

From the principle of conservation of energy which is used in first law of thermodynamics, it has been established that;

When gas is compressed, temperature increases and when gas expands, temperature decreases.

The mathematical form of the first law of thermodynamics is;

Q  =  U  +  W   ---(eq 1)

Where,  

Q  = the total heat transferred,  

U  = the internal energy and  

W  = the work done.

When we differentiate the equation above, we will get;

Δ Q  =  Δ U  +  Δ W  ---(eq 2)

We are told in the question, that the gas is well insulated. This means the walls of the container of the container carrying the gas is well insulated. We can as a result of the insulation, say that there is no heat transfer between the system and the environment.

Thus;

Δ Q  =  0  

∴ the work done is given as;

Δ W  =  P Δ V

Putting P Δ V for Δ W in eq 2 gives;

Δ Q  =  Δ U  +  P Δ V

Since Δ Q  =  0, then;

Δ U  +  P Δ V = 0

Δ U  = -P Δ V

  • When gas is compressed, the final volume will be less than the initial volume and as such Δ V will be negative. This means that Δ U will be positive which denotes that it increases which is a sign of increase in temperature.

  • In contrast, when the gas expands, the final volume will be more than the initial volume and as such Δ V will be positive. This means that Δ U will be negative which denotes that it decreases which is a sign of decrease in temperature.

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