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The nonvolatile, nonelectrolyte sucrose, C12H22O11 (342.3 g/mol), is soluble in water H2O.
Calculate the osmotic pressure (in atm) generated when 12.8 grams of sucrose are dissolved in 278 mL of a water solution at 298 K.

Respuesta :

Answer: The osmotic pressure of the solution is 3.29 atm

Explanation:

To calculate the concentration of solute, we use the equation for osmotic pressure, which is:

[tex]\pi=iMRT[/tex]

or,

[tex]\pi=i\times \frac{\text{Mass of solute}\times 1000}{\text{Molar mass of solute}\times \text{Volume of solution (in mL)}}\times RT[/tex]

where,

[tex]\pi[/tex] = osmotic pressure of the solution = ?

i = Van't hoff factor = 1 (for non-electrolytes)

Mass of sucrose = 12.8 grams

Molar mass of sucrose = 342.3 g/mol

Volume of solution = 278 mL

R = Gas constant = [tex]0.082\text{ L atm }mol^{-1}K^{-1}[/tex]

T = temperature of the solution = 298 K

Putting values in above equation, we get:

[tex]\pi=1\times \frac{12.8\times 1000}{342.3\times 278}\times 0.0821\text{ L. atm }mol^{-1}K^{-1}\times 298K\\\\\pi=3.29atm[/tex]

Hence, the osmotic pressure of the solution is 3.29 atm