Iron (Fe) undergoes an allotropic transformation at 912C: upon heating from a BCC (phase) to an FCC ( phase). Accompanying this transformation is a change in the atomic radius of Fe—from rBCC = 0.12584 nm to rFCC = 0.12894 nm—and, in addition a change in density (and volume). Compute the percent volume change associated with this reaction. Does the volume increase or decrease?

Respuesta :

The percent volume change associated with this reaction is 97.66 %.

What is allotropic transformation?

Allotropic transformation is a change in the physical form of material.

Given, rBCC = 0.12584 nm

rFCC = 0.12894

Step 1: For a rBCC (α phase) structure, the unit cell length and atomic radius is equal

[tex]\sqrt{ (3a_B_C_C_ )}4R_B_C_C\\\\\\a_B_C_C=\dfrac{(4R_B_C_C)}{\sqrt{3} }[/tex]

[tex]a_B_C_C=\dfrac{4\times 0.12584}{\sqrt{3} }=0.2906\; nm[/tex]

Now, for rFCC,

[tex]a_B_C_C=\dfrac{(4R_F_C_C)}{\sqrt{2} }[/tex]

[tex]a_B_C_C=\dfrac{4\times 0.12894 }{\sqrt{3} }= 0.3647\; nm[/tex]

Step 2: The percent volume change is:

[tex]\bigtriangleup V= \dfrac{(V_f-V_i)}{V_initial} \times100[/tex]

[tex]\bigtriangleup V & =\dfrac{( V_F_C_C3) -(V_B_C_C3)}{〖V_B_C_C3 } \times100 = \dfrac{0.3647}{0.2906} \times100 = 97.66 \%[/tex]

Thus, the percent volume change is 97.66 %

Learn more allotropic transformation, here:

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