A 2.950×10−2 M solution of glycerol (C3H8O3) in water is at 20.0∘C. The sample was created by dissolving a sample of C3H8O3 in water and then bringing the volume up to 1.000 L. It was determined that the volume of water needed to do this was 998.7 mL . The density of water at 20.0∘C is 0.9982 g/mL. Part A Calculate the molality of the glycerol solution.

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Answer:

The molality of the glycerol solution is 2.960×10^-2 mol/kg

Explanation:

Number of moles of glycerol = Molarity × volume of solution = 2.950×10^-2 M × 1 L = 2.950×10^-2 moles

Mass of water = density × volume = 0.9982 g/mL × 998.7 mL = 996.90 g = 996.90/1000 = 0.9969 kg

Molality = number of moles of glycerol/mass of water in kg = 2.950×10^-2/0.9969 = 2.960×10^-2 mol/kg

Considering the solution of molality, molarity and density, the molality of the glycerol solution is 0.029 [tex]\frac{moles}{kg}[/tex].

Molality is a measure of concentration that indicates the ratio of the number of moles of any dissolved solute to kilograms of solvent.

The Molality of a solution is determined by the expression:

[tex]Molality=\frac{number of moles of solute}{kilograms of solvent}[/tex]

Molality is expressed in units [tex]\frac{moles}{kg}[/tex].

In this case, you know a 2.950×10⁻² M solution of glycerol (C₃H₈O₃) in water is at 20.0∘C. The sample was created by dissolving a sample of C₃H₈O₃ in water and then bringing the volume up to 1 L.

So, being the molarity the number of moles of solute that are dissolved in a certain volume and determined by the following expression:

[tex]Molarity=\frac{number of moles of solute}{volume}[/tex]

the number of moles of solute can be calculated as:

number of moles of solute= molarity× volume

Then, in this case, the number of moles of solute is calculated as:

number of moles of solute= 2.950×10⁻² M× 1 L

Solving:

number of moles of solute= 2.950×10⁻² moles

On the other side, density is a quantity that allows us to measure the amount of mass in a certain volume of a substance. Then, the expression for the calculation of density is the quotient between the mass of a body and the volume it occupies:

[tex]density=\frac{mass}{volume}[/tex]

Then, the mass can be calculated as:

mass= density×volume

In this case, you know that the volume of water needed was 998.7 mL  and the density of water at 20.0∘C is 0.9982 g/mL. So the mass of water can be calculated as:

mass of water= mass of solvent= 0.9982 g/mL× 998.7 mL= 996.9 g= 0.9969 kg

Finally, the molality is calculated as:

[tex]Molality=\frac{2.950x10^{-2} moles}{0.9969 kg}[/tex]

Solving:

Molality= 0.029 [tex]\frac{moles}{kg}[/tex]

In summary, the molality of the glycerol solution is 0.029 [tex]\frac{moles}{kg}[/tex].

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