A 200-mg sample of a purifed compound of unknown molar mass is dissolved in benzene and diluted with that solvent to a volume of 25.0 cm3 . The resulting solution is found to have an osmotic pressure of 0.0105 atm at 300 K. What is the molar mass of the unknown compound?

Respuesta :

Answer: The molar mass of the unknown compound is 18765.7 g/mol

Explanation:

[tex]\pi =CRT[/tex]

[tex]\pi[/tex] = osmotic pressure  = 0.0105 atm

C= concentration in Molarity

R= solution constant  = 0.0821 Latm/Kmol

T= temperature = 300 K

For the given solution: 200 mg or 0.2 grams of unknown compound is dissolved in 25 ml of solution.

[tex]Molarity=\frac{\text{Mass of solute}\times 1000}{\text{Molar mass of solute}\times \text{volume of solution in ml}}[/tex]

Putting in the values we get:

[tex]C=\frac{0.2\times 1000}{M\times 25}[/tex]

[tex]0.0105 =\frac{0.2\times 1000}{M\times 25}\times 0.0821\times 300[/tex]

[tex]M=18765.7g/mol[/tex]

The molar mass of the unknown compound is 18765.7 g/mol