Consider one mole of a monatomic ideal gas at 300 K that expands isothermally from a volume of 1 m^3 to 10 m^3.

a) What is the energy change of the gas?
b) What is the entropy change of the gas?
c) What is the Helmholtz energy change of the gas?
d) What is the enthalpy change of the gas?
e) What is the Gibbs energy change of the gas?

Respuesta :

Answer:

a. Zero

b.  19 J

c.  - 5700 J

d. Zero

e. Zero

Explanation:

a. In an isothermal process, the change in temperature is zero. There are inter-molecular forces and the gas particles have perfect collision.  

b. The entropy is given as

ΔS = nRln[tex]\frac{V2}{V1}[/tex]

     = 1 (8.314)ln (10/1)

     = 19 J

c. The Helmholtz energy change is given by A = U - TS

                                                                              =  0 - (300× 19)

                                                                              = 5 700 J

d. For an ideal gas, the mathematical equation for  enthalpy, H with internal energy, E and PV can be expressed as:

H = U + PV

It follows that:

ΔH = ΔU + Δ(PV)

     = ΔU + Δ(nRT)

However, in the question, Δn = 0, because the gas is mono atomic, there is no change in the number of moles and also he process if isothermal. Therefore,

ΔH = ΔU

However, for an isothermal process, the change in internal energy is ΔU = 0

Note that the equations are applicable to ideal gases.

e. The gas expansion is isothermal, so there is no temperature change. Therefore, energy change is zero.