Respuesta :

Answer:

Approximately [tex]2.47\times 10^{15}\; \rm Hz[/tex].

Explanation:

The Lyman Series of a hydrogen atom are due to electron transitions from energy levels [tex]n \ge 2[/tex] to the ground state where [tex]n = 1[/tex]. In this case, the electron responsible for the line started at [tex]n = 2[/tex] and transitioned to

A hydrogen atom contains only one electron. As a result, Bohr Model provides a good estimate of that electron's energy at different levels.

In Bohr's Model, the equation for an electron at energy level [tex]n[/tex] (

[tex]\displaystyle - \frac{k\, Z^2}{n^2}[/tex] (note the negative sign in front of the fraction,)

where

  • [tex]k = 2.179 \times 10^{-18}\; \rm J[/tex] is a constant.
  • [tex]Z[/tex] is the atomic number of that atom. [tex]Z = 1[/tex] for hydrogen.
  • [tex]n[/tex] is the energy level of that electron.

The electron that produced the [tex]n = 2[/tex] line was initially at the

[tex]\begin{aligned} &E_{n = 2} \cr &= -\frac{k\, Z^2}{n^2} \cr &= -\frac{2.179 \times 10^{-18} \times 1}{2^2} \cr & \approx -5.4475\times 10^{-19}\; \rm J\end{aligned}[/tex].

The electron would then transit to energy level [tex]n = 1[/tex]. Its energy would become:

[tex]\begin{aligned} &E_{n = 1} \cr &= -\frac{k\, Z^2}{n^2} \cr &= -\frac{2.179 \times 10^{-18} \times 1}{1^2} \cr & \approx -2.179 \times 10^{-18} \; \rm J\end{aligned}[/tex].

The energy change would be equal to

[tex]\begin{aligned}&\text{Initial Energy} - \text{Final Energy} \cr &= E_{n = 2} - E_{n = 1} \cr &= -5.4475 \times 10^{-19} - \left(-2.179 \times 10^{-18}\right) \cr & \approx 1.63425\times 10^{-18}\; \rm J \end{aligned}[/tex].

That would be the energy of a photon in that [tex]n = 2[/tex] spectrum line. Planck constant [tex]h[/tex] relates the frequency of a photon to its energy:

[tex]E = h \cdot f[/tex], where

  • [tex]E[/tex] is the energy of the photon.
  • [tex]h \approx 6.62607015\times 10^{-34}\; \rm J \cdot s[/tex] is the Planck constant.
  • [tex]f[/tex] is the frequency of that photon.

In this case, [tex]E \approx 1.63425 \times 10^{-18}\; \rm J[/tex]. Hence,

[tex]\begin{aligned} f &= \frac{E}{h} \cr &\approx \frac{1.63425\times 10^{-18}}{6.62607015\times 10^{-34}} \cr & \approx 2.47 \times 10^{15}\; \rm s^{-1}\end{aligned}[/tex].

Note that [tex]1 \; \rm Hz = 1 \; \rm s^{-1}[/tex].