Determine the mass of a nonvolatile, nonionizing compound that must be added to 4.79 kg of water to lower the freezing point to -1.3°C if the molar mass of the compound is 50.0 g/mol.

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Answer:

The mass we used from the solute is 175 g

Explanation:

ΔT = Kf . m . i → Formula for colligative property of freezing point depression

ΔT = T° freezing of pure solvent - T° freezing of solution

0°C - (-1.3°C) = 1.3 °C

Kf if the cryoscopic constant of solvent. In this case, for water and the value is 1.86 °C/m

m = molality → moles of solute / 1 kg of solvent

Let's replace → 1.3°C = 1.86°C . m

m = 1.3°C / 1.86 m  → 0.731 mol/kg

0.731 mol/kg is the molality, moles of solute in 1kg of solvent. But in this solution we do not have 1 kg of solvent, we have 4.79 kg. So:

0.731 mol/kg . 4.79 kg = 3.501 moles

This is the moles of the solute we used, so let's convert them to mass:

3.501 mol . 50 g / 1 mol = 175 g

Note: Freezing point depression formula is completed with the Van't Hoff factor (i); this number corresponds to the ions dissolved in the solution.

In this case the solute is non volatile and nonionizing, so i = 1

ΔT = Kf . m . i

The mass of a nonvolatile, nonionizing compound is 175 g.

Freezing point depression:

Freezing point depression is a colligative property observed in solutions that results from the introduction of solute molecules to a solvent. It is given by:

ΔT =kf *i*m

ΔT = T° freezing of pure solvent - T° freezing of solution

0°C - (-1.3°C) = 1.3 °C

kf = constant of solvent. In this case, for water and the value is 1.86 °C/m

Molality:

It is a measure of the number of moles of solute in a solution corresponding to 1 kg or 1000 g of solvent.

m = molality → moles of solute / 1 kg of solvent

Let's replace → 1.3°C = 1.86°C . m

m = 1.3°C / 1.86 m  → 0.731 mol/kg

→ Calculation for number of moles:

0.731 mol/kg . 4.79 kg = 3.501 moles

This is the moles of the solute we used, so let's convert them to mass:

3.501 mol . 50 g / 1 mol = 175 g

It offers the  on the colligative properties of solutions.

In this case the solute is non volatile and nonionizing, so i = 1

ΔT = Kf . m . i

Thus, the  mass of a nonvolatile, nonionizing compound is 175 g.

Find more information about Molality here:

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