Answer : The integer 'x' in the hydrate is, 2
Explanation : Given,
Mass of hydrate [tex]Na_2CO_3[/tex] = 4.31 g
Mass of anhydrous [tex]Na_2CO_3[/tex] = 3.22 g
First we have to calculate the mass of water.
Mass of water = Mass of hydrate [tex]Na_2CO_3[/tex] - Mass of anhydrous [tex]Na_2CO_3[/tex]
Mass of water = 4.31 g - 3.22 g
Mass of water = 1.09 g
Now we have to calculate the moles of [tex]H_2O[/tex] and [tex]Na_2CO_3[/tex]
[tex]\text{Moles of }H_2O=\frac{\text{Mass of }H_2O}{\text{Molar mass of }H_2O}[/tex]
Molar mass of [tex]H_2O[/tex] = 18 g/mol
[tex]\text{Moles of }H_2O=\frac{1.09g}{18g/mol}=0.0605mol[/tex]
and,
[tex]\text{Moles of }Na_2CO_3=\frac{\text{Mass of }Na_2CO_3}{\text{Molar mass of }Na_2CO_3}[/tex]
Molar mass of [tex]Na_2CO_3[/tex] = 106 g/mol
[tex]\text{Moles of }Na_2CO_3=\frac{3.22g}{106g/mol}=0.0303mol[/tex]
Now we have to calculate the ratio of [tex]H_2O[/tex] and [tex]Na_2CO_3[/tex]
[tex]\frac{H_2O}{Na_2CO_3}=\frac{0.0605mol}{0.0303mol}=1.99\approx 2[/tex]
The formula of compound is, [tex]Na_2CO_3.xH_2O[/tex]
The value of 'x' is, 2
So, the formula of compound is, [tex]Na_2CO_3.2H_2O[/tex]
Thus, the integer 'x' in the hydrate is, 2