A mixture of 0.307 M Cl 2 , 0.465 M F 2 , and 0.706 M ClF is enclosed in a vessel and heated to 2500 K . Cl 2 ( g ) + F 2 ( g ) − ⇀ ↽ − 2 ClF ( g ) K c = 20.0 at 2500 K Calculate the equilibrium concentration of each gas at 2500 K .

Respuesta :

Answer: The equilibrium concentration of chlorine gas, fluorine gas and ClF gas is 0.159 M, 0.317 M and 1.002 M respectively.

Explanation:

We are given:

Initial concentration of chlorine gas = 0.307 M

Initial concentration of fluorine gas = 0.465 M

Initial concentration of ClF gas = 0.706 M

The given chemical equation follows:

                            [tex]Cl_2(g)+F_2(g)\rightleftharpoons 2ClF(g)[/tex]

Initial:                  0.307       0.465       0.706

At eqllm:           0.307-x    0.465-x       0.706+2x

The expression of [tex]K_c[/tex] for above equation follows:

[tex]K_c=\frac{[ClF]^2}{[Cl_2][F_2]}[/tex]

We are given:

[tex]K_c=20.0[/tex]

Putting values in above equation, we get:

[tex]20.0=\frac{(0.706+2x)^2}{(0.307-x)(0.465-x)}\\\\x=0.148,0.993[/tex]

Neglecting the value of x = 0.993 because the equilibrium concentrations of chlorine and fluorine gases will become negative, which is not possible

So, equilibrium concentration of chlorine gas = (0.307 - x) = [0.307 - 0.148] = 0.159 M

Equilibrium concentration of fluorine gas = (0.465 - x) = [0.465 - 0.148] = 0.317 M

Equilibrium concentration of ClF gas = (0.706 + 2x) = [0.706 + 2(0.148)] = 1.002 M

Hence, the equilibrium concentration of chlorine gas, fluorine gas and ClF gas is 0.159 M, 0.317 M and 1.002 M respectively.

The equilibrium concentration of Chlorine is 0.159 M, Fluorine is 0.317 M, and ClF is 1.002 M.

According to the given chemical equation,1 mole of chlorine reacts with 1 mole of fluorine to give 2 moles of chlorine fluoride.

The initial concentration of Chlorine = 0.307 M

Fluorine = 0.465 M

Chlorine fluoride = 0.706 M.

After equilibrium, the formation of ClF will be 0.706 + 2x

Fluorine = 0.465 - x

Chlorine = 0.307 - x

The expression of [tex]\rm K_c[/tex] = [tex]\rm \dfrac{[ClF]^2}{[Cl_2]\;[F_2]}[/tex]

The expression of [tex]\rm K_c[/tex] = [tex]\rm \dfrac{(0.706\;+\;2x)^2}{(0.307\;-\;x)\;(0.465\;-\;x)}[/tex]

20 = [tex]\rm \dfrac{(0.706\;+\;2x)^2}{(0.307\;-\;x)\;(0.465\;-\;x)}[/tex]

x = 0.148

The concentration of  ClF will be 0.706 + 2x = 0.706 + 2(0.148)

The concentration of  ClF = 1.002 M

The concentration of Fluorine = 0.465 - 0.148

The concentration of Fluorine = 0.317 M

The concentration of Chlorine = 0.307 - 0.148

The concentration of Chlorine = 0.159 M.

For more information about the equilibrium concentration, refer to the link:

https://brainly.com/question/16645766