A 350 mL saturated solution of magnesium hydroxide, Mg(OH)2 is prepared at 25 degrees Celsius. The solubility product constant, Ksp, for Mg(OH)2 is 1.8 x 10^-11 at 25 degrees Celsius.
1) Find the molar solubility of Mg(OH)2 at 25 degrees Celsius?

2) What is the concentration (mol/L) of hydroxide ion, OH-, in the saturated solution at 25 degrees Celsius?

Respuesta :

Answer:

For 1: The solubility of magnesium hydroxide at 25°C is [tex]1.65\times 10^{-4}M[/tex]

For 2: The concentration of hydroxide ion in the saturated solution at 25°C is [tex]3.3\times 10^{-4}M[/tex]

Explanation:

  • For 1:

The equation for the ionization of the magnesium hydroxide is given as:

             [tex]Mg(OH)_2\leftrightharpoons Mg^{2+}+2OH^-[/tex]

                                    s            2s

Expression for the solubility product of [tex]Mg(OH)_2[/tex] will be:

[tex]K_{sp}=[Mg^{2+}][OH^-]^2\\\\K_{sp}=s\times (2s)^2=4s^3[/tex]

We are given:

[tex]K_{sp}=1.8\times 10^{-11}[/tex]

Putting values in above equation, we get:

[tex]1.8\times 10^{-11}=4s^3\\\\s=1.65\times 10^{-4}M[/tex]

Hence, the solubility of magnesium hydroxide at 25°C is [tex]1.65\times 10^{-4}M[/tex]

  • For 2:

Concentration of hydroxide ion in the solution = 2s = [tex](2\times 1.65\times 10^{-4})=3.3\times 10^{-4}M[/tex]

Hence, the concentration of hydroxide ion in the saturated solution at 25°C is [tex]3.3\times 10^{-4}M[/tex]