Suppose that in the synthesis of isoamyl acetate, a student began with 6.289 grams of acetic acid and 3.75 grams of isoamyl alcohol. If the mass of isoamyl acetate obtained were 4.828, what was the percent yield?

Respuesta :

Answer: The percent yield of the reaction is 87.24 %.

Explanation:

To calculate the number of moles, we use the equation:

[tex]\text{Number of moles}=\frac{\text{Given mass}}{\text{Molar mass}}[/tex]     .....(1)

  • For acetic acid:

Given mass of acetic acid = 6.289 g

Molar mass of acetic acid = 60 g/mol

Putting values in equation 1, we get:

[tex]\text{Moles of acetic acid}=\frac{6.289g}{60g/mol}=0.105mol[/tex]

  • For isoamyl alcohol:

Given mass of isoamyl alcohol = 3.75 g

Molar mass of isoamyl alcohol = 88.15 g/mol

Putting values in equation 1, we get:

[tex]\text{Moles of isoamyl alcohol}=\frac{3.75g}{88.15g/mol}=0.0425mol[/tex]

The chemical equation for the reaction of acetic acid and isoamyl alcohol follows:

[tex]\text{Acetic acid + Isoamyl alcohol}\rightarrow \text{Isoamyl acetate}[/tex]

By Stoichiometry of the reaction:

1 mole of isoamyl alcohol reacts with 1 mole of acetic acid

So, 0.0425 moles of isoamyl alcohol will react with = [tex]\frac{1}{1}\times 0.0425=0.0425mol[/tex] of acetic acid

As, given amount of acetic acid is more than the required amount. So, it is considered as an excess reagent.

Thus, isoamyl alcohol is considered as a limiting reagent because it limits the formation of product.

By Stoichiometry of the reaction:

1 mole of isoamyl alcohol produces 1 mole of isoamyl acetate

So, 0.0425 moles of isoamyl alcohol will produce = [tex]\frac{1}{1}\times 0.0425=0.0425moles[/tex] of isoamyl acetate

Now, calculating the mass of isoamyl acetate from equation 1, we get:

Molar mass of isoamyl acetate = 130.2 g/mol

Moles of isoamyl acetate = 0.0425 moles

Putting values in equation 1, we get:

[tex]0.0425mol=\frac{\text{Mass of isoamyl acetate}}{130.2g/mol}\\\\\text{Mass of isoamyl acetate}=(0.0425mol\times 130.2g/mol)=5.534g[/tex]

  • To calculate the percentage yield of isoamyl acetate, we use the equation:

[tex]\%\text{ yield}=\frac{\text{Experimental yield}}{\text{Theoretical yield}}\times 100[/tex]

Experimental yield of isoamyl acetate = 4.828 g

Theoretical yield of isoamyl acetate = 5.534 g

Putting values in above equation, we get:

[tex]\%\text{ yield of isoamyl acetate}=\frac{4.828g}{5.534g}\times 100\\\\\% \text{yield of isoamyl acetate}=87.24\%[/tex]

Hence, the percent yield of the reaction is 87.24 %.