At a certain temperature, 0.900 mol SO 3 is placed in a 2.00 L container. 2 SO 3 ( g ) − ⇀ ↽ − 2 SO 2 ( g ) + O 2 ( g ) At equilibrium, 0.110 mol O 2 is present. Calculate K c .

Respuesta :

Answer: The value of [tex]K_c[/tex] is 0.0057

Explanation:

Initial moles of  [tex]SO_3[/tex] = 0.900 mole

Volume of container = 2.00 L

Initial concentration of [tex]SO_3=\frac{moles}{volume}=\frac{0.900moles}{2.00L}=0.450M[/tex]  

equilibrium concentration of [tex]O_2=\frac{moles}{volume}=\frac{0.110mole}{2.00L}=0.055M[/tex] [/tex]

The given balanced equilibrium reaction is,

                            [tex]2SO_3(g)\rightleftharpoons 2SO_2(g)+O_2(g)[/tex]

Initial conc.              0.450 M               0        0

At eqm. conc.    (0.450 -2x) M         (2x) M   (x) M

The expression for equilibrium constant for this reaction will be,

[tex]K_c=\frac{[O_2][SO_2]^2}{[SO_3]^2}[/tex]

[tex]K_c=\frac{x\times (2x)^2}{0.450-2x)^2}[/tex]

we are given : x = 0.055

Now put all the given values in this expression, we get :

[tex]K_c=\frac{0.055\times (2\times 0.055)^2}{0.450-2\times 0.055)^2}[/tex]

[tex]K_c=0.0057[/tex]

Thus the value of the equilibrium constant is 0.0057