A 0.100 mole quantity of a monoprotic acid HA is added to 1.00 L of pure water. When equilibrium is reached, the pH of the solution is 3.75. What is the value of Ka for the acid HA

Respuesta :

Answer:

[tex]3.167\times 10^{-7}[/tex] is the value of [tex]K_a[/tex]for the acid HA.

Explanation:

The pH of the solution = 3.75

The hydrogen ion concentration :

[tex]pH=-log[H^+][/tex]

[tex]3.75=-\log[H^+][/tex]

[tex][H^+]=10^{-3.75}=0.0001778 M[/tex]

Concentration of weak acid = 0.100 mole/L

[tex]HA\rightleftharpoons H^++A^-[/tex]

Initually

0.100 M    0   0

At equilibrium

(0.100-x)M     x    x

The expression of dissociation constant can be given as:

[tex]K_a=\frac{x\times x}{(0.100-x)}[/tex]

Here the value of x = [tex][H^+]=0.0001778 M[/tex]

[tex]K_a=\frac{0.0001778 M\times 0.0001778 M}{(0.100-0.0001778)M }[/tex]

[tex]K_a=3.167\times 10^{-7}[/tex]

[tex]3.167\times 10^{-7}[/tex] is the value of [tex]K_a[/tex]for the acid HA.