The rate consnt for a reaction is measured as a function of temperature. A plot of ln k versus 1/T is linear and has s slope of -1.01 x 1-^4K. Calculate the activation energy for the reaction

Respuesta :

Answer : The activation energy for the reaction is, [tex]8.39\times 10^4J[/tex]

Explanation :

According to the Arrhenius equation,

[tex]K=A\times e^{\frac{-Ea}{RT}}[/tex]

Taking logarithm on both side, we get:

[tex]\ln K=\frac{-Ea}{RT}+\ln A[/tex]

where,

[tex]Ea[/tex] = activation energy for the reaction

R = gas constant = 8.314 J/mole.K

T = temperature

K = rate constant

A = pre-exponential factor

The linear equation expression is:

y = mx + c

Plot of ln (K) versus (1/T) gives a straight line with a slope is equal to, [tex]\frac{-Ea}{R}[/tex]

As we are given that:

Slope = [tex]-1.01\times 10^4K[/tex]

So,

[tex]Slope=\frac{-Ea}{R}=-1.01\times 10^4K[/tex]

[tex]-Ea=-1.01\times 10^4K\times R[/tex]

[tex]Ea=1.01\times 10^4K\times 8.314J/mol.K[/tex]

[tex]Ea=83971.4J=8.39\times 10^4J[/tex]

Thus, the activation energy for the reaction is, [tex]8.39\times 10^4J[/tex]