Aqueous sulfuric acid (H2SO4) reacts with solid sodium hydroxide (NaOH) to produce aqueous sodium sulfate (Na2SO4) and liquid water (H2O). What is the theoretical yield of sodium sulfate formed from the reaction of 3.9 g of sulfuric acid and 1.8g of sodium hydroxide?

Respuesta :

Answer: The theoretical yield of [tex]Na_2SO_4[/tex] is, 5.65 grams.

Explanation : Given,

Mass of [tex]H_2SO_4[/tex] = 3.9 g

Mass of [tex]NaOH[/tex] = 7.8 g

Molar mass of [tex]H_2SO_4[/tex] = 98 g/mol

Molar mass of [tex]NaOH[/tex] = 40 g/mol

First we have to calculate the moles of [tex]H_2SO_4[/tex] and [tex]NaOH[/tex].

[tex]\text{Moles of }H_2SO_4=\frac{\text{Given mass }H_2SO_4}{\text{Molar mass }H_2SO_4}[/tex]

[tex]\text{Moles of }H_2SO_4=\frac{3.9g}{98g/mol}=0.0398mol[/tex]

and,

[tex]\text{Moles of }NaOH=\frac{\text{Given mass }NaOH}{\text{Molar mass }NaOH}[/tex]

[tex]\text{Moles of }NaOH=\frac{7.8g}{40g/mol}=0.195mol[/tex]

Now we have to calculate the limiting and excess reagent.

The balanced chemical equation is:

[tex]H_2SO_4+2NaOH\rightarrow Na_2SO_4+2H_2O[/tex]

From the balanced reaction we conclude that

As, 1 mole of [tex]H_2SO_4[/tex] react with 2 mole of [tex]NaOH[/tex]

So, 0.0398 moles of [tex]H_2SO_4[/tex] react with [tex]0.0398\times 2=0.0796[/tex] moles of [tex]NaOH[/tex]

From this we conclude that, [tex]NaOH[/tex] is an excess reagent because the given moles are greater than the required moles and [tex]H_2SO_4[/tex] is a limiting reagent and it limits the formation of product.

Now we have to calculate the moles of [tex]Na_2SO_4[/tex]

From the reaction, we conclude that

As, 1 mole of [tex]H_2SO_4[/tex] react to give 1 mole of [tex]Na_2SO_4[/tex]

So, 0.0398 mole of [tex]H_2SO_4[/tex] react to give 0.0398 mole of [tex]Na_2SO_4[/tex]

Now we have to calculate the mass of [tex]Na_2SO_4[/tex]

[tex]\text{ Mass of }Na_2SO_4=\text{ Moles of }Na_2SO_4\times \text{ Molar mass of }Na_2SO_4[/tex]

Molar mass of [tex]Na_2SO_4[/tex] = 142 g/mole

[tex]\text{ Mass of }Na_2SO_4=(0.0398moles)\times (142g/mole)=5.65g[/tex]

Therefore, the theoretical yield of [tex]Na_2SO_4[/tex] is, 5.65 grams.