The effusion rate of an unknown gas is measured and found to be 31.50 mL/min. Under identical experimental conditions, the effusion rate of O2 is found to be 30.50 mL/min. If the choices are CH4, CO, NO, CO2, and NO2, what is the identity of the unknown gas

Respuesta :

Answer : The unknown gas is, NO

Solution :

According to the Graham's law, the rate of effusion of gas is inversely proportional to the square root of the molar mass of gas.

[tex]R\propto \sqrt{\frac{1}{M}}[/tex]

or,

[tex](\frac{R_2}{R_1})=\sqrt{\frac{M_1}{M_2}}[/tex]       ..........(1)

where,

[tex]R_1[/tex] = rate of effusion of unknown gas  = 31.50 mL/min

[tex]R_2[/tex] = rate of effusion of [tex]O_2[/tex] gas  = 30.50 mL/min

[tex]M_1[/tex] = molar mass of unknown gas = ?

[tex]M_2[/tex] = molar mass of [tex]O_2[/tex] gas = 32 g/mole

Now put all the given values in the above formula 1, we get:

[tex](\frac{30.50mL/min}{31.50mL/min})=\sqrt{\frac{M_1}{32g/mole}}[/tex]

[tex]M_1=30.0g/mol[/tex]

From the this we conclude that the unknown gas is, NO that has 30.0 g/mol molar mass.

Hence, the unknown gas is, NO