For the reaction H2 S(g) + I2 (s) ⇌ S(s) + 2 HI(g) Kp = 1.33×10–5 at 333 K. What will be the total pressure of the gases above an equilibrium mixture if, at equilibrium, PHI = 0.010 × PH2 S?

Respuesta :

Answer:  The total pressure of the gases above an equilibrium mixture is 0.1343 atm

Explanation:-

Equilibrium constant is defined as the ratio of concentration of products to the concentration of reactants each raised to the power their stoichiometric ratios. It is expressed as [tex]K_p[/tex]

For the given chemical reaction:

[tex]H_2S(g)+I_2(g)\rightarrow S(g)+2HI(g)[/tex]

The expression for [tex]K_p[/tex] is written as:

[tex]K_p=\frac{(p_{HI})^2}{(p_{H_2S})^1}[/tex]

[tex]K_p=1.33\times 10^{-5}[/tex]

[tex]1.33\times 10^{-5}=\frac{p_{HI}^2}{p_{H_2S}^1}[/tex]

[tex]1.33\times 10^{-5}=\frac{(0.010\times p_{H_2S})^2}{p_{H_2S}^1}[/tex]

[tex]p_{H_2S}=0.133[/tex]

[tex]p_{HI}=0.010\times 0.133=0.0013[/tex]

Total pressure at equilibrium = [tex]p_{H_2S}+p_{HI}[/tex] = 0.133+0.0013 = 0.1343 atm