The normal freezing point of water is 0oC and it's freezing point depression constant is 1.86oC/m. If a 2.00 molal solution of Na2SO4 is prepared, what is the freezing point of the mixture?

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Answer:

[tex]\large \boxed{\text{-11.2 $^{\circ}$C}}[/tex]

Explanation:

The formula for the change in freezing point ΔT_f caused by an electrolyte is

[tex]\Delta T_{f} = -iK_{f}b[/tex]

1. Calculate i

Na₂SO₄(aq) ⟶ 2Na⁺(aq) + SO₄²⁻(aq)

1 mol Na₂SO₄ gives 3 mol ions.

i = 3

2. Calculate the freezing point

(a) Change in freezing point

[tex]\Delta T_{f} = -iK_{f}b = -3 \times 1.86 \times 2.00 = -11.2 \,^{\circ}\text{C}[/tex]

(b) Freezing point

[tex]\Delta T_{f} = T_{f} - T_{i}\\ T_{f} = \Delta T_{f} + T_{i} = 0.00 - 11.22 = \large \boxed{\textbf{-11.2 $^{\circ}$C }}[/tex]

Answer:

The answer is -11.16°C

Explanation: