A gas has density 0.87 g/L at 30oC and 131.2 kPa.

Find density at STP.

*Hint use the density of gases equation.

a
.57 g/L
b
.72 g/L
c
.75 g/L
d
.54 g/L

Respuesta :

Answer:

  • Option C. 0.75g/L

Explanation:

Using your hint, the density of gases equation is:

        [tex]d=\dfrac{p\times M}{R\times T}[/tex]

Where:

  • d = density of the gas
  • M = molar mass of the gas
  • R = universal constant of gases
  • T = absolute temperature

The conditions of your gas are:

State 1:

  • d₁ = 0.87g/L
  • T₁ = 30 + 273.15K = 303.15K
  • p₁ = 131.2kPa

State 2 (STP):

  • d₂ = ?
  • T₂ = 0 + 273.15K = 273.15K
  • p₂ = 100kPa (in the old definition of STP it was 101.325kPa)

Since M and R are constants, the density of gases equation drives to:

      [tex]\dfrac{d_1\times T_1}{p_1}=\dfrac{d_2\times T_2}{p_2}[/tex]

Now you can substitute and clear d₂

       [tex]\dfrac{0.87g/L\times 303.15K}{131.2kPa}=\dfrac{d_2\times 273.15K}{100kPa}[/tex]

  • d₂ = 0.74g/L

If you use 101.325kPa instead of 100kPa it will result 0.75g/L, which is the option C.