Answer:
Cl < S < P < Na
Explanation:
We have to understand the trend for effective nuclear charge before answering the question;
The periodic table tendency for effective nuclear charge: Increase across a period (due to increasing nuclear charge with no accompanying increase in shielding effect). Decrease down a group (although nuclear charge increases down a group, shielding effect more than counters its effect).
Based on this, the elements can be arranged in the following order;
In decreasing order;
Cl < S < P < Na